Two cases must be differentiated: In the first case the verb is negated, in the second case the 都 dōu.
都 dōu (= all) + 不 bù (= not) + verb
不 bù (= not) + 都 dōu (= all) + verb
他 | 们 | 都 | 不 | 是 | 德 | 国 | 人 | 。 |
tā | men | dōu | bù | shì | dé | guó | rén | _ |
he | pl suffix | all | not | be | virtue | country | person | _ |
they | all, both, already, even | no, not, after negative question: yes | to be, correct, yes | a German | 。 | |||
All of them are not Germans (= none of them is German). |
他 | 们 | 不 | 都 | 是 | 德 | 国 | 人 | 。 |
tā | men | bù | dōu | shì | dé | guó | rén | _ |
he | pl suffix | not | all | be | virtue | country | person | _ |
they | no, not, after negative question: yes | all, both, already, even | to be, correct, yes | a German | 。 | |||
Not all of them are Germans. |